Analisis Aspek Molekuler Biomarka Alkana Bercabang Core Badak 1/208 Muara Badak, Kutai Kartanegara, Kalimantan Timur

R. Arizal Firmansyah*  -  Jurusan Pendidikan Kimia, FITK Universitas Islam Negeri Walisongo, Jawa Tengah, Indonesia
R. Y. Perry Burhan  -  Jurusan Kimia, Institut Teknologi Sepuluh Nopember Surabaya, Indonesia

(*) Corresponding Author
Study compound biomarka branched alkanes on core 1/208 Rhinos have done to contribute to the activities of oil exploration wells 1/208 Muara Badak Badak, East Kalimantan's Kutai Kartanegara-through core biomarka profile branched alkanes. Core samples extracted by alternately with solvent mixture of toluene-methanol (3: 1) and chloroform-methanol (3: 1). Then fractionated by Column Chromatography and Thin Layer Chromatography to obtain aliphatic hydrocarbon fraction. Fractions obtained were identified using Gas Chromatography-Mass Spectrometry.The content biomarka aliphatichydrocarbon fraction were identified, among others, iso and anteiso alkanes, mono and trimethyl alkanes. Compounds iso and anteiso alkanes, and alkyl alkane other, providing information that the source of organic material core samples I and II is derived from microorganisms prokaryotic or biogenic precursor derived from cyanobacteria (marine microorganisms) and homologous monomethyl alkanes found in core samples II closer homologous series monomethyl alkanes found in sediments and oil and Precambrian Proterozoic era, so it can be said that the core sample II core samples older than I.

Keywords: Biomarka;branched alkanes;Core Badak

  1. R.D. Putrohari, Pentingnya Data Eksplorasi Sebelum Pengeboran. http://www.migasreview.com/post/1422860880/-pentingnya-data-eksplorasi-sebelum-pengeboran.html (diakses 1 Agustus 2015). Seaway (USA). Organic Geochemistry. 32 (2013) 949-954.
  2. H. Kenig, D.J. Simons, and K.B. Anderson, Distribution and origin of ethyl-branched alkanes in a Cenomanian transgressive shale of the Western Interior (2001).
  3. R.E. Summons, Branched alkanes from ancient and modern sediments: Isomer discrimination by GC/MS with multiple reaction monitoring. Organic Geochemistry. 11 (1987) 281-289.
  4. B. Warton, R. Alexander, and R.I. Kagi, The effect of maturation on the distribution of monoethylalkanes in Late Cretaceous sedimentary rocks and crude oils from the Gippsland Basin, Australia. Organic Geochemistry. 29 (1998) 593-604.
  5. R. Ishiwatari, H. Uemura, S. Yamamoto, Hopanoid hydrocarbons and perylene in Lake Biwa (Japan) sediments: Environmental control on their abundance and molecular composition. Organic Geochemistry. 76 (2014) 194-203.
  6. S.R. Yawanarajah and M.A Kruge, Lacustrine shales and oil shales from Stellarton Basin, Nova Scotia, Canada: organofacies variations and use of polyaromatic hydrocarbons as maturity indicators. Organic Geochemistry. 21 (1994) 153-170.
  7. S. Li, Q. Shi, X. Pang, B. Zhang, H. Zhang, Origin of the unusually high dibenzothiophene oils in Tazhong-4 Oilfield of Tarim Basin and its implication in deep petroleum exploration. Organic Geochemistry. 48 (2012) 56-80.
  8. H. Carstens, Finding Oil – Using Geochemistry (2008).
  9. http://www.geoexpro.com/articles/2008/05/finding-oil-using-geochemistry. (diakses 1 agustus 2015).
  10. R.D. McCarthy and A.H. Duthie, A Rapid Quantitative Method for The Separation of Free Fatty Acids from Other Lipids”, J. Lipid Research, 3 (1962) 117-119.
  11. J. Köster, J.K. Volkman, J. Rullköter, B.M Scholz-Böttcher, J. Rethmeir, and U. Fischer, Mono-, Di-, and Trimethyl-Branched Alkanes in Cultures of The Filamentous Cyanobacterium Calothrix Scopulorum, Organic Geochemistry, 30 (1999) 1367-1379.
  12. B.A. Whitton, The biology of Rivulariaceae. In: Fay, P., van Baalen, C. (Eds.), The Cyanobacteria. Elsevier, Amsterdam (1987).
  13. R.E. Summons, T.G. Powell, C.J. Boreham, Petroleum Geology and Geochemistry of the Middle Proterozoic McArthur Basin, Northern Australia: III. Composition of Extractable Hydrocarbons, Geochimica et Cosmochimica Acta, 52 (1988)1747-1763.
  14. M.G. Fowler, and A.G. Douglas, Saturated Hydrocarbon Biomarkers in Oils of Late Precambrian Age from Eastern Siberia”, Organic Geochemistry, 11 (1987) 201-213.

Open Access Copyright (c) 2016 Journal of Natural Sciences and Mathematics Research
Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Journal of Natural Sciences and Mathematics Research
Published by Faculty of Science and Technology
Universitas Islam Negeri Walisongo Semarang

Jl Prof. Dr. Hamka Kampus III Ngaliyan Semarang 50185
Website: https://journal.walisongo.ac.id/index.php/JNSMR
Email:jnsmr@walisongo.ac.id

ISSN: 2614-6487 (Print)
ISSN: 2460-4453 (Online)

View My Stats

Lisensi Creative Commons

This work is licensed under a Creative Commons Lisensi Creative Commons .

apps