Analysis the Effect of Activated Natural Zeolites for Fe Metal Adsorption

Fadliah Fadliah; Christin Palit; Reno Pratiwi; Reza Aryanto; Tri Widayati Putri

doi:10.21580/wjc.v6i2.17291

Analysis the Effect of Activated Natural Zeolites for Fe Metal Adsorption

* - Department of Mining Engineering, Universitas Trisakti, Jakarta, Indonesia

- Department of Mining Engineering, Universitas Trisakti, Jakarta, Indonesia

- Department of Petroleum Engineering, Universitas Trisakti, Jakarta, Indonesia

- Department of Mining Engineering, Universitas Trisakti, Jakarta, Indonesia

- Fishery Technology of Institute of Technology and Business Maritime Balik Diwa, Makassar, Indonesia

(*) Corresponding Author

DOI: 10.21580/wjc.v6i2.17291

Abstract
References
Licensing
How to cite

Zeolite, as an adsorbent, can be improved by a chemical activation process. In this study, zeolite was activated using the acid activation method by soaking natural zeolite with HCl and HF, and the activated zeolite was then used to adsorb Fe metal. Zeolite was characterized using SEM and XRD, and the adsorption capacity of the zeolite was analyzed using AAS. The results of SEM analysis show that zeolite after activation has a more significant number of pores than zeolite before activation. The results of XRD analysis show that zeolite that has been activated has a higher content of quartz (SiO2) and clinoptilolite than zeolite that has not been activated. The results of the zeolite adsorption capacity and efficiency test on Fe metal showed that the most excellent adsorption capacity was when the contact time was 60 minutes, with adsorption capacity and adsorption efficiency values of 3.2403 mg/g and 97.21%.

Keywords: Zeolite; activation; acid; Fe metal

Akhtar, F., Andersson, L., Ogunwumi, S., Hedin, N., B. and Om, L. (2014) ‘Structuring adsorbents and catalysts by processing of porous powders’, J. Eur. Ceram. Soc, 34(7), pp. 1643–1666. doi:https://doi.org/10.1016/J.JEURCERAMSOC.2014.01.008.
Dionisiou, N.S., Matsi, T. (2016) ‘Natural and surfactant-modified zeolite for the removal of pollutants (mainly inorganic) from natural waters and wastewaters’, Environ. Mater. Waste: Resour. Recov. Pollut. Prevention, pp. 591–606. doi:https://doi.org/10.1016/ B978-0-12-803837-6.00023-8.
Fadliah, F. et al. (2021) ‘Analysis of the Zeolite Size Effect on the Content of Chemical Compounds in Acid Activated Natural Zeolite’, Journal of Earth Energy Science, Engineering, and Technology, 4(3). doi:10.25105/jeeset.v4i3.10227.
Fatimah, Sri, R. E., Charissa, D.S. (2021) ‘Pengaruh Ukuran Partikel Zeolit Alam yang Diaktivasi dan Diimpregnasi HCl dan Mg2+ pada Penjerapan Ion Fosfat’, Jurnal Teknik Kimia USU, 10(1), pp. 13–18.
Ginting, A.Br., Dian, A., Sutri, I., dan K. (2007) ‘Karakterisasi Komposisi Kimia, Luas Permukaan Pori dan Sifat Termal dari Zeolit Bayah, Tasikmalaya dan Lampung.’, J.Tek. Bhn. Nukl, 3(1), pp. 1–48.
Gutti, B., Aji, MM., Magaji, G. (2012) ‘Environmental impact of natural resources exploitation in nigeria and the way forward’, Int. J. Applied Technology in Environmental Sanitation, (2), pp. 95–102.
Irannajad, M., Kamran Haghighi, H. (2020) ‘Removal of heavy metals from polluted solutions by zeolitic adsorbents: a review’, Environ. Processes, 8(1), pp. 7–35. doi:https:// doi.org/10.1007/S40710-020-00476-X, 2020 8:1.
Jim´enez-Casta˜neda, M.E., Medina, D.. (2017) ‘Use of surfactant-modified zeolites and clays for the removal of heavy metals from water’, Water, 9(4), p. 235. doi:https://doi.org/ 10.3390/W9040235.
Kusdarto (2008) ‘Potensi Zeolit Indonesia’, Jurnal Zeolit Indonesia, VII(2), pp. 78–87.
Liu and Jiaqi, Cheng, X., Zhang, Y., Wang, X., Zou, Q., Fu, L. (2017) ‘Zeolite modification for adsorptive removal of nitrite from aqueous solutions’, Microporous Mesoporous Mater, (252), pp. 179–187. doi:https://doi.org/10.1016/J.MICROMESO.2017.06.029.
Marantos, Ioannis, Christidis, George, E., Ulmanu, M. (2012) Zeolite formation and deposits. In: Handbook of Natural Zeolites. United Arab Emirates: Bentham Science Publishers Sharjah.
Margeta, K., Zabukovec, N., Siljeg, M., Farkas, A. (2013) ‘Natural Zeolites in Water Treatment – How Effective Is Their Use’, Water Treatment [Preprint]. doi:https://doi.org/10.5772/ 50738.
Oktaviani, R., Noor, H., dan Aman, S.. (2019) ‘Modifikasi dan Karakterisasi Zeolit Alam Tasikmalaya dengan Fe2O3. Jurnal Atomik’, Jurnal Atomik, 4(1), pp. 30–35.
Oztas¸, N.A., Karabakan, A., Topal, O. (2008) ‘Removal of Fe(III) ion from aqueous solution by adsorption on raw and treated clinoptilolite samples’, Microporous Mesoporous Mater, 111(1–3), pp. 200–205. doi:. https://doi.org/10.1016/J.MICROMESO.2007.07.030.
Reeve, P.J., Fallowfield, H.. (2018) ‘Natural and surfactant modified zeolites: a review of their applications for water remediation with a focus on surfactant desorption and toxicity towards microorganisms’, J. Environ. Manag, (205), pp. 253–261. doi:https://doi.org/ 10.1016/J.JENVMAN.2017.09.077.
Renni, C. P., F. Widhi, W., dan Nuni, W. 2018 (2018) ‘Pemanfaatan Zeolit Alam Teraktivasi sebagai Adsorben Ion Logam Fe(III) dan Cr(VI)’, Indo. J. Chem. Sci, 7(1), pp. 64–70.
Shi, J., Yang, Z., Dai, H., Lu, X., Peng, L., Tan, X., Shi, L., Fahim, R. (2018) ‘Preparation and application of modified zeolites as adsorbents in wastewater treatment.’, Water Sci. Technol, (3), pp. 621–635. doi:https://doi.org/10.2166/WST.2018.249, 2017.
Taneva, N. (2012) ‘Removal of ammonium and phosphates from aqueous solutions by activated and modified Bulgarian clinoptilolite’, J. Chem. Eng. Mater. Sci, 3(5), pp. 79–85. doi:https://doi.org/10.5897/JCEMS11.028.
Wang, Y.F., Lin, F., Pang, W.. (2007) ‘Ammonium exchange in aqueous solution using Chinese natural clinoptilolite and modified zeolite’, . J. Hazard Mater, 142(1–2), pp. 160–164. doi:https://doi.org/10.1016/j.jhazmat.2006.07.074.
Yuna, Z. (2016) ‘Review of the natural, modified, and synthetic zeolites for heavy metals removal from wastewater’, Enviromental Engineering Science, 33(7), pp. 443–454.