MALACHITE GREEN TRANSPORT USING POLYMER INCLUSION MEMBRANE METHOD WITH co-EDVB AS CARRIER

Kharisma Citra Aprilia; Nurul Ulfa  Safitri; Khusna Arif Rakhman; Agung Abadi Kiswandono

doi:10.21580/wjc.v8i1.25826

Authors

Kharisma Citra Aprilia Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Lampung, Lampung, Indonesia
Nurul Ulfa Safitri Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Lampung, Indonesia
Khusna Arif Rakhman Department of Chemistry Education, Faculty of Teacher Training and Education, University of Khairun Ternate, Indonesia
Agung Abadi Kiswandono Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Lampung, Indonesia

DOI:

https://doi.org/10.21580/wjc.v8i1.25826

Keywords:

Copoly Eugenol Divinyl Benzene, Malachite Green, Polymer Inclusion Membrane, Selective Transport, Wastewater

Abstract

Malachite green (MG) is a synthetic dye known for its toxic and carcinogenic properties, necessitating effective removal from aquatic environments. This study investigated the use of a polymer inclusion membrane (PIM) containing co-poly(eugenol-divinylbenzene) (co-EDVB) 2% as a carrier for the selective transport of MG. The membrane was prepared by dissolving co-EDVB, polyvinyl chloride, and dibenzyl ether in tetrahydrofuran (THF). Several parameters were evaluated, including the pH of the source phase, the concentration of nitric acid in the receiving phase, membrane thickness, carrier concentration, transport time, and competitive transport in synthetic wastewater. UV-Visible spectrophotometric analysis at a wavelength of 613 nm revealed that the transport efficiency reached 90.95% under optimal conditions: source phase pH 7, 0.50 M HNO₃ in the receiving phase, membrane thickness T54, and 18 hours of transport. In the presence of competing metal ions such as Pb²⁺ and Cu²⁺, the efficiency decreased to 80.79%, confirming the important role of co-EDVB in enhancing transport selectivity and efficiency.

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References

Abhijeet Pathy, Nageshwari Krishnamoorthy, Scott X. Chang, B.P. (2022) ‘Malachite green removal using algal biochar and its composites with kombucha SCOBY: An integrated biosorption and phycoremediation approach’, Surfaces and Interfaces, 30, p. 101880. Available at: https://doi.org/https://doi.org/10.1016/j.surfin.2022.101880.

Candra Saka, Agung Abadi Kiswandono, S.H. (2020) ‘Synthesis Of Polymer Inclusion Membranes Based On Pvc Containing Copoly-Edvb 4% As A Carrier For Removal Of Phenol Solutions’, Pollution Research Journal, 39(4), pp. 1009–1016. Available at: https://www.envirobiotechjournals.com/PR/v39i420/Poll Res-25.pdf.

Faheem Uddin (2021) ‘Environmental hazard in textile dyeing wastewater from local textile industry’, Cellulose, 28, pp. 10715–10739. Available at: https://doi.org/https://doi.org/10.1007/s10570-021-04228-4.

Guoke Zhao, H.Z. (2020) ‘Cation–π Interactions in Graphene-Containing Systems for Water Treatment and Beyond’, Advanced materials, 33(2), p. 1905756. Available at: https://doi.org/https://doi.org/10.1002/adma.201905756.

He, J. et al. (2023) ‘Strategies for Solving the Issue of Malachite Green Residues in Aquatic Products: A Review’, Aquaculture Research, 2023, pp. 1–17. Available at: https://doi.org/10.1155/2023/8578570.

Jalilvand, P. et al. (2020) ‘Optimizing of malachite green extraction from aqueous solutions using hydrophilic and hydrophobic nanoparticles’, Journal of Molecular Liquids, 308, p. 113014. Available at: https://doi.org/10.1016/j.molliq.2020.113014.

Jyotshana Sharma, Shubhangani Sharma, V.S. (2023) ‘Toxicity of malachite green on plants and its phytoremediation: A review’, Regional Studies in Marine Science, 62, p. 102911. Available at: https://doi.org/https://doi.org/10.1016/j.rsma.2023.102911.

Kaczorowska, M.A., Bożejewicz, D. and Witt, K. (2023) ‘The Application of Polymer Inclusion Membranes for the Removal of Emerging Contaminants and Synthetic Dyes from Aqueous Solutions—A Mini Review’, Membranes, 13(2). Available at: https://doi.org/10.3390/membranes13020132.

Khairati, R.M., Kiswandono, A.A. and Ihwan, D. (2025) ‘Jurnal Kimia Sains dan Aplikasi Application of Polymer Inclusion Membrane in the Transport of Malachite Green Dye Using Copolymer ( Eugenol-Diallyl Phthalate )’, Jurnal Kimia Sains dan Aplikasi, 28(1), pp. 8–15.

Khalid, N.A. et al. (2022) ‘Fabrication and Characterisation of MWCNT/Polyvinyl (PVC) Polymer Inclusion Membrane for Zinc (II) Ion Removal from Aqueous Solution’, Membranes, 12(10). Available at: https://doi.org/10.3390/membranes12101020.

Kiswandono, A.A., Widiarto, S., et al. (2022) ‘Kompetisi Fenol pada Limbah Buatan Menggunakan Kopoli-Eugenol Divinil Benzena 10% sebagai Senyawa Pembawa’, Alchemy Jurnal Penelitian Kimia, 18(1), p. 1. Available at: https://doi.org/10.20961/alchemy.18.1.45356.1-9.

Kiswandono, A.A., Nusantari, C.S., et al. (2022a) ‘Optimization and Evaluation of Polymer Inclusion Membranes Based on PVC Containing Copoly-EDVB 4% as a Carrier for the Removal of Phenol Solutions’, Membranes, 12(3), pp. 1009–1016. Available at: https://doi.org/10.3390/membranes12030295.

Kiswandono, A.A., Nusantari, C.S., et al. (2022b) ‘Optimization and Evaluation of Polymer Inclusion Membranes Based on PVC Containing Copoly-EDVB 4% as a Carrier for the Removal of Phenol Solutions’, Membranes, 12(3). Available at: https://doi.org/10.3390/membranes12030295.

Kiswandono, A.A. et al. (2023) ‘Investigating Phenol Transport Using Copoly(Eugenol-DVB) 8% as a Carrier with the Supported Liquid Membrane Method’, Jurnal Kimia Sains dan Aplikasi, 26(10), pp. 372–380. Available at: https://doi.org/10.14710/jksa.26.10.372-380.

Kiswandono, A.A., Aprilia, K.C., et al. (2024) ‘Evaluation of Polymer Inclusion Membrane Containing Copoly Eugenol Divinyl Benzene 10% as a Carrier for Phenol Transport’, Journal of Advanced Research in Fluid Mechanics and Thermal Sciences, 122(2), pp. 38–51. Available at: https://doi.org/10.37934/arfmts.122.2.3851.

Kiswandono, A.A., Sindiani, A.V., et al. (2024) ‘Transport of Malachite Green Using the Polyeugenol-Based Polymer Inclusion Membrane (PIM) Method’, Journal of Membrane Science and Research, 10(1), pp. 1–5. Available at: https://doi.org/10.22079/JMSR.2023.2013382.1635.

Macías, M. and Rodríguez de San Miguel, E. (2023) ‘On the Use of Polymer Inclusion Membranes for the Selective Separation of Pb(II), Cd(II), and Zn(II) from Seawater’, Membranes, 13(5). Available at: https://doi.org/10.3390/membranes13050512.

Mancilla-Rico, A.J. and Rodríguez de San Miguel, E. (2022) ‘Simultaneous determination of Cu(II), Zn(II), and Pb(II) from aqueous solutions using a polymer inclusion membrane (PIM) based-sensor with 1-(2-pyridylazo)-2-naphthol (PAN) as chromophore and chemometric methods’, Frontiers in Analytical Science, 2(September), pp. 1–20. Available at: https://doi.org/10.3389/frans.2022.971352.

Prasetya, N.B.A. et al. (2020) ‘Effects of percent weight of divinylbenzene as crosslinking agent on the properties of eugenol-divinylbenzene copolymers’, Journal of Physics: Conference Series, 1524(1). Available at: https://doi.org/10.1088/1742-6596/1524/1/012089.

R.Sarathi, L. Renuga Devi, N.L. Sheeba, E. Selva Esakki, S.M.S. (2023) ‘Review Article : Photocatalytic degradation of malachite green dye by metal oxide nanoparticles-mini’, J. Chem. Rev, 5(1), pp. 15–30.

Soo, J.A.L. et al. (2021) ‘Characterization and kinetic studies of poly(Vinylidene fluoride-co-hexafluoropropylene) polymer inclusion membrane for the malachite green extraction’, Membranes, 11(9). Available at: https://doi.org/10.3390/membranes11090676.

Teixeira, Y.N. et al. (2022) ‘Malachite green removal using ionic flocculation’, Water Practice and Technology, 17(5), pp. 1113–1128. Available at: https://doi.org/10.2166/wpt.2022.054.

Waseem Ullah Khan, Sirajuddin Ahmed, Yogesh Dhoble, S.M. (2023) ‘A critical review of hazardous waste generation from textile industries and associated ecological impacts’, Journal of the Indian Chemical Society, 100(1), p. 100829. Available at: https://doi.org/https://doi.org/10.1016/j.jics.2022.100829.

Yikun Xu, Jing Zhang, G.J. and Zhao, P. (2024) ‘Evaluating malachite green removal from aqueous solution by hydroxyl enhanced hydrochar and biomass’, Biomass Conv. Bioref, 14, pp. 14391–14404. Available at: https://doi.org/https://doi.org/10.1007/s13399-022-03647-y.

Yusuf, A. et al. (2020) ‘A review of emerging trends in membrane science and technology for sustainable water treatment’, Journal of Cleaner Production, 266, p. 121867. Available at: https://doi.org/10.1016/j.jclepro.2020.121867.