Ag-ZSM-11 Zeolite Synthesis Using Silica from Elephant Grass for LED Application

Authors

  • Citra D. D. Sundari Department of Chemistry Education, UIN Sunan Gunung Djati Bandung, Indonesia
  • Soni Setiadji Department of Chemistry, Faculty of Science and Technology, UIN Sunan Gunung Djati Bandung, Indonesia
  • Atthar Luqman Firmansyah Master Program in Computational Science, Faculty of Mathematic and Natural Science, Institut Teknologi Bandung, Indonesia
  • Dede Abdurahman Graduate Program in Chemistry Education, UIN Sunan Gunung Djati Bandung, Indonesia
  • Denia Febby Nurbaeti Graduate Program in Chemistry Education, UIN Sunan Gunung Djati Bandung, Indonesia

DOI:

https://doi.org/10.21580/wjc.v2i2.3107

Keywords:

silica isolation, elephant grass, zeolite, ZSM-11, LED

Abstract

Silica (SiO2) has been successfully isolated from elephant grass by the sol gel method through pH regulation using NaOH and HCl. The resulting silica has an amorphous character with crystalline phase impurities. The isolated silica was then used as a source of silica for the synthesis of ZSM-11 zeolite using the hydrothermal method with a ratio of SiO2 : TBAOH : H2O = 1 : 0.35 : 25. XRD characterization results confirmed the formation of ZSM-11 zeolite. The SEM results show that the ZSM-11 zeolite crystal morphology is oval with crystal growth in all directions. Immersion of the synthesized ZSM-11 zeolite into AgNO3 solution and followed by calcination resulted in zeolite Ag-ZSM-11 which has different optical properties compared to the initial ZSM-11 zeolite. Zeolite ZSM-11 gives purple luminescence while zeolite Ag-ZSM-11 gives pink luminescence when illuminated under UV lights

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References

Bhandari, S., Pramanik, S., Khandelia, R., Chattopadhyay, A.. 2016. Gold Nanocluster and Quantum Dot Complex in Protein for Biofriendly White-Light-Emitting Material. ACS Appl. Mater. Interfaces. 8, 1600.

Zheng, J., Dickson, R. M.. 2002. Individual Water-Soluble Dendrimer-Encapsulated Silver Nanodot Fluorescence. J. Am. Chem. Soc. 124, 13982.

Temboury, M. R. C., Paolucci, V., Hooley, E. N., Latterini, L., Vosch, T.. 2016. Probing DNA-stabilized fluorescent silver nanocluster spectral heterogeneity by time-correlated single photon counting. Analyst. 141(1), 123.

Kunwar, P., Hassinen, J., Bautista, G., Ras, R. H. A., Toivonen, J. 2014. Direct Laser Writing of Photostable Fluorescent Silver Nanoclusters in Polymer Films. ACS Nano. 8 (11), 11165-71.

Yu, J., Patel, S. A., Dickson, R. M. 2007. In vitro and intracellular production of peptide-encapsulated fluorescent silver nanoclusters. Angew. Chem. Int. Ed. 46 (12), 2028-30.

Royon, A., Bourhis, K., Bellec, M., Papon, G., Bousquet, B., Deshayes, Y., Cardinal, T., Canioni, L. 2010. Silver clusters embedded in glass as a perennial high capacity optical recording medium. Adv. Mater. 22 (46), 5282-6.

Coutino-Gonzalez, E., Grandjean, D., Roeffaers, M., Kvashnina, K., Fron, E., Dieu, B., De Cremer, G., Lievens,P., Sels, B., Hofkens, J. 2014. X-ray irradiation-induced formation of luminescent silver clusters in nanoporous matrices. Chem. Commun. 50 (11), 1350-2.

Van Oers, C. J., Kurttepeli, M., Mertens, M., Bals, S., Meynen, V., Cool, P. 2014. Zeolite β nanoparticles based bimodal structures: Mechanism and tuning of the porosity and zeolitic properties. Microporous Mesoporous Mater. 185, 204-212.

De Cremer, G., Coutiño-Gonzalez, E., Roeffaers, M. B. J., Moens, B., Ollevier, J., Van der Auweraer, M., Schoonheydt, R., Jacobs, P. a., De Schryver, F. C., Hofkens, J., De Vos, D. E., Sels, B. F., Vosch, T. 2009. Characterization of fluorescence in heat-treated silver-exchanged zeolites. J. Am. Chem. Soc. 131 (8), 3049-56.

Fenwick, O., Coutino-Gonzalez, E., Grandjean, D., Baekelant, W., Richard, F., Bonacchi, S., De Vos, D., Lievens, P., Roeffaers, M., Hofkens, J., Samori, P. 2016. Tuning the energetics and tailoring the optical properties of silver clusters confined in zeolites. Nat. Mater. 15(9), 1017-22.

Vosch, T., Sels, B. F., Roeffaers, M. B. J., Hofkens, J., De Vos, D. E., De Cremer, G. 2009. BE2008/0050 (WO 2009006707).

Vosch, T., Sels, B. F., Roeffaers, M. B. J., Hofkens, J., De Vos, D. E., De Cremer, G. 2009. BE2008/0051 (WO 2009006707).b

Schwabegger, G., Dingemans, T., Resel, R., Sitter, H., Simbrunner, C. 2014. Non-doped, blue-emitting, color-stable, organic light-emitting diode based on 2,2′: 6’,2″-ternaphthalene. Appl. Phys. A: Mater. Sci. Process. 115 (3), 731-35.

Kennes, K., Coutino-Gonzalez, E., Martin, C., Baekelant, W., Roeffaers, M.B. J., Van der Auweraer, M. 2017. Silver Zeolite Composites-Based LEDs: A Novel Solid-State Lighting Approach. Adv. Funct. Mater. 27 (14), 1606411.

Vaibhav, V., Vijayalakshmi, U., Roopan, S. M. 2015. Agricultural waste as a source for the production of silica nanoparticles. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 139, 515.

Nakanishi, E.Y., Frías, M., Martínez-Ramírez, S., Santos, S. F., Rodrigues, M. S., Rodríguez, O., Savastano Jr., H. 2014. Characterization and properties of elephant grass ashes as supplementary cementing material in pozzolan/Ca(OH)2 pastes. Construction and Building Materials. 73, 391.

Nakanishi, E. Y., Frías, M., Santos, S. F., Rodrigues, M. S., de la Villa, R. V., Rodriguez, O., Junior, H. S. 2016. Investigating the possible usage of elephant grass ash to manufacture the eco-friendly binary cements. J. Clean. Prod. 116, 236-43.

Strezov V., Evans T. J., Hayman C. 2008. Thermal conversion of elephant grass (Pennisetum Purpureum Schum) to bio-gas, bio-oil and charcoal. Bioresource Technology. 99, 8394–8399.

Srisittipokakun, N., Sangwaranatee, N. 2014. Comparative Study of Physical and Optical Properties of Glasses from SiO2 and Napier Ash. Adv. Mat. Res. 979, 401.

Shim, J., Velmurugan, P., Oh, B-T. 2015. Extraction and physical characterization of amorphous silica made from corn cob ash at variable pH conditions via sol gel processing. J. Indust. Eng. Chem. 30, 249-53.

Mozgawa, W., Krol, M., and Barczyk, K. 2011. FT-IR Studies of Zeolites from Different Structural Groups. Chemik, 65 (7), 667-674.

Lu, M., Cheng, Y., Pan, S.-l., Wei, G.-y. 2014. Des. Wat. Treat. 57, 1.

Dey, K. P., Gosh, S., Naskar, M. K. 2012. A facile synthesis of ZSM-11 zeolite particles using rice husk ash as silica source. Mat. Lett. 87, 87-89.

Zhang, L., Liu, S., Xie, S., Xu, L. 2012. Organic template-free synthesis of ZSM-5/ZSM-11 co-crystalline zeolite. Mic. Mes. Mat. 147, 117

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Published

2018-12-09