Preparation of Cellulose Pineapple (Ananas comosus) Peel   as Adsorbent of Remazol Yellow Dye

Intan Lestari; Edwin Permana; Dara Shalsa Billah Hidayat; Dhian Eka Wijaya

doi:10.21580/wjc.v6i2.14540

Preparation of Cellulose Pineapple (Ananas comosus) Peel as Adsorbent of Remazol Yellow Dye

* - Department of Chemistry, Faculty of Science and Technology, Universitas Jambi, Indonesia

- Department of Industrial Chemistry, Faculty of Science and Technology, Universitas Jambi, Indonesia

- Department of Chemistry, Faculty of Science and Technology, Universitas Jambi, Indonesia

(*) Corresponding Author

DOI: 10.21580/wjc.v6i2.14540

Abstract
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The extraction of cellulose from pineapple (Ananas comosus) peel has been carried out through delignification using alkaline and hydrolysis with acid. The extraction of cellulose was carried out by de-waxing, delignification followed by hydrolysis with H₂SO₄ acid. The cellulose obtain was identified by FTIR and SEM-EDS. The results showed that the FTIR spectra of pineapple peel cellulose contain hydroxyl and carboxyl functional groups which useful in the adsorption process. The morphology of cellulose has a more homogeneous and porous shape. The cellulose obtained was used for adsorption of Remazol yellow dye by studying adsorption parameters, namely the effect of pH, contact time and solution concentration. The adsorption process was obtained at pH 2, the optimum contact time was 30 minutes and concentration at 100 mg/L with an adsorption capacity is 19.888 mg/g.

Keywords: Extraction, cellulose, pine apple, adsorption, Remazol yellow

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Xia, M. et al. (2019) ‘Removal of Hg(ii) in aqueous solutions through physical and chemical adsorption principles’, RSC Advances, 9(36), pp. 20941–20953. doi: 10.1039/c9ra01924c.
Zhang, Y. et al. (2019) ‘Appraisal of Cu(ii) adsorption by graphene oxide and its modelling: Via artificial neural network’, RSC Advances, 9(52), pp. 30240–30248. doi: 10.1039/c9ra06079k.
Arianti, W. D., Pramitasari, H. A. and Widodo, L. U. (2022) ‘Penyerapan Zat Warna Remazol Red Menggunakan Adsorben Arang Aktif Batang Ubi Kayu’, ChemPro, 3(1), pp. 14–19. doi: 10.33005/chempro.v3i1.128.
Chan, C. H. et al. (2015) ‘Cellulose nanofibrils: A rapid adsorbent for the removal of methylene blue’, RSC Advances, 5(24), pp. 18204–18212. doi: 10.1039/c4ra15754k.
Deivy Andhika Permata et al. (2021) ‘Delignification of Lignocellulosic Biomass’, World Journal of Advanced Research and Reviews, 12(2), pp. 462–469. doi: 10.30574/wjarr.2021.12.2.0618.
Handayani, D. S. et al. (2016) ‘Adsorption of remazol yellow FG from aqueous solution on chitosan-linked P-T-Butylcalix[4]Arene’, IOP Conference Series: Materials Science and Engineering, 107(1). doi: 10.1088/1757-899X/107/1/012011.
Jović, M. et al. (2013) ‘Study of the electrochemical oxidation of reactive textile dyes using platinum electrode’, International Journal of Electrochemical Science, 8(1), pp. 168–183.
Lestari, D. Y. and Laksono, E. W. (2020) ‘Kinetics and thermodynamics studies of copper(II) adsorption onto activated carbon prepared from salacca zalacca peel’, Molekul, 15(2), pp. 63–72. doi: 10.20884/1.jm.2020.15.2.530.
Lestari, I., Prasetyo, E. and Gusti, D. R. (2021) ‘PENGGUNAAN KARBON AKTIF MAGNETIT-Fe3O4 SEBAGAI PENYERAP ZAT WARNA REMAZOL YELLOW’, Journal BiGME, 1(1), pp. 29–37. doi: 10.22437/bigme.v1i1.12311.
Lyu, H. et al. (2017) ‘Removal of hexavalent chromium from aqueous solutions by a novel biochar supported nanoscale iron sulfide composite’, Chemical Engineering Journal, 322, pp. 516–524. doi: 10.1016/j.cej.2017.04.058.
Mandal, A. and Chakrabarty, D. (2011) ‘Isolation of nanocellulose from waste sugarcane bagasse (SCB) and its characterization’, Carbohydrate Polymers, 86(3), pp. 1291–1299. doi: 10.1016/j.carbpol.2011.06.030.
Mondal, N. K. and Chakraborty, S. (2020) ‘Adsorption of Cr(VI) from aqueous solution on graphene oxide (GO) prepared from graphite: equilibrium, kinetic and thermodynamic studies’, Applied Water Science, 10(2), pp. 1–10. doi: 10.1007/s13201-020-1142-2.
Morán, J. I. et al. (2008) ‘Extraction of cellulose and preparation of nanocellulose from sisal fibers’, Cellulose, 15(1), pp. 149–159. doi: 10.1007/s10570-007-9145-9.
Pardo, M. E. S. et al. (2014) ‘Chemical Characterisation of the Industrial Residues of the Pineapple (Ananas comosus)’, Journal of Agricultural Chemistry and Environment, 03(02), pp. 53–56. doi: 10.4236/jacen.2014.32b009.
Rajasulochana, P. and Preethy, V. (2016) ‘Comparison on efficiency of various techniques in treatment of waste and sewage water – A comprehensive review’, Resource-Efficient Technologies, 2(4), pp. 175–184. doi: 10.1016/j.reffit.2016.09.004.
Saravanakumar, S. S. et al. (2013) ‘Characterization of a novel natural cellulosic fiber from Prosopis juliflora bark’, Carbohydrate Polymers, 92(2), pp. 1928–1933. doi: 10.1016/j.carbpol.2012.11.064.
Sehaqui, H. et al. (2014) ‘Enhancing adsorption of heavy metal ions onto biobased nanofibers from waste pulp residues for application in wastewater treatment’, Cellulose, 21(4), pp. 2831–2844. doi: 10.1007/s10570-014-0310-7.
Sheltami, R. M. et al. (2012) ‘Extraction of cellulose nanocrystals from mengkuang leaves (Pandanus tectorius)’, Carbohydrate Polymers, 88(2), pp. 772–779. doi: 10.1016/j.carbpol.2012.01.062.
Silva, L. S. et al. (2013) ‘Dye anionic sorption in aqueous solution onto a cellulose surface chemically modified with aminoethanethiol’, Chemical Engineering Journal, 218, pp. 89–98. doi: 10.1016/j.cej.2012.11.118.
Silva, Lucinaldo S. et al. (2018) ‘Effective Removal of the Remazol Yellow GR Dye Using Cellulose Functionalized by Basic Groups’, Water, Air, and Soil Pollution, 229(7). doi: 10.1007/s11270-018-3864-4.
Silva, Lucinaldo S et al. (2018) ‘Penghapusan Efektif Pewarna Remazol Yellow GR Menggunakan Selulosa Difungsikan oleh Kelompok Dasar’.
Sun, X. F. et al. (2005) ‘Characteristics of degraded cellulose obtained from steam-exploded wheat straw’, Carbohydrate Research, 340(1), pp. 97–106. doi: 10.1016/j.carres.2004.10.022.
Xia, M. et al. (2019) ‘Removal of Hg(ii) in aqueous solutions through physical and chemical adsorption principles’, RSC Advances, 9(36), pp. 20941–20953. doi: 10.1039/c9ra01924c.
Zhang, Y. et al. (2019) ‘Appraisal of Cu(ii) adsorption by graphene oxide and its modelling: Via artificial neural network’, RSC Advances, 9(52), pp. 30240–30248. doi: 10.1039/c9ra06079k.