Utilization of Silver Nanoparticles as Adsorbent of Methylene Blue

Nindita Clourisa Amaris Susanto*  -  Vocational School, Universitas Sebelas Maret, Surakarta, Indonesia
Nadiatul Fajri  -  Department of Chemistry, Faculty of Science and Technology, Universitas Jambi, Indonesia
Yoga Pratama  -  Department of Chemistry, Faculty of Science and Technology, Universitas Jambi, Indonesia
M. Reza Prasetio  -  Department of Chemistry, Faculty of Science and Technology, Universitas Jambi, Indonesia
Rahayu Rahayu  -  Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Pattimura, Ambon, Indonesia
Aulia Ratri Hapsari  -  School of Chemistry, University of Birmingham, United Kingdom

(*) Corresponding Author

This study has successfully synthesized silver nanoparticles (Ag NPs) using banana stem extract as the bioreductor and reported its application in adsorption of methylene blue (MB). Adsorption of MB was tested under ultraviolet light by varying pH solution values (3, 4, 5, 7, 9, 10, and 11), irradiation times (0,5, 1, 2, 3, 4, 5 hours), and MB concentrations (50, 100, 150, and 200 ppm) to determine their optimum values. The results revealed that the optimum pH value and irradiation time were at 9 and 1 hour, demonstrating the highest deconcentration percentage (%D) of 89.19% and 94.58%, respectively. The %D of MB dye by samples with concentrations of 50, 100, 150, and 200 ppm were 86.294%, 78.416%, 69.366%, and 66.638%, respectively, with an average of %D of 75.189%. The least degraded MB was 90.643 mg, obtained at 50 ppm. Meanwhile, the most degraded MB was 280.181 mg, attained at 200 ppm. The average concentration of degraded MB was 188.538 mg/gr.

Keywords: silver nanoparticles; adsorption; methylene blue

  1. Arifin, N. 2016. Synthesis of Silver Nanoparticles Using Guava Leaf Bioreductor (Psidium Guajava L.) Using Microwave Irradiation. Indonesian Journal of Chemical Science. 5 (3):195–201.
  2. Benhachem, F. Z., Attar, T., & Bouabdallah, F. 2019. Kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbon. Chemical Review and Letters, 2(1), 33-39.
  3. Bere, M. L., S. James dan M. Manurung. 2019. Synthesis of Silver Nanoparticles (Npag) Using Water Extract of Basil Leaves (Ocimum Sanctum Linn.) and Its Application in Photodegradation of Methylene Blue Dyes. Cakra Kimia (Indonesian E-Journal of Applied Chemistry). 7 (2):155–164.
  4. Chen, C. H., Lin, Y. C., Mao, C. F., & Liao, W. T. 2019. Green synthesis, size control, and antibacterial activity of silver nanoparticles on chitosan films. Research on Chemical Intermediates, 45, 4463-4472.
  5. Fajri, N., Putri, L. F. A., Prasetio, M. R., Azizah, N., Pratama, Y., & Susanto, N. C. A. (2022). Potential of Banana Stem (Musa paradisiaca l) as a bioreductor in Green Synthesis of Ag Nanoparticles. Jurnal Penelitian Sains, 24(1), 33-37.
  6. Gavhane, A., Padmanabhan, P., Kamble, S. P., dan Jangle, S. N. 2012. Synthesis of Nanoparticles Using Extract of Neem Leaf and Triphala and Evalution of Their Antimicrobial Activities. International Journal of Pharma Bio Sciences, 3(3): 88-100.
  7. Huda, T dan T.K.Yulitaningtyas. 2018. Methylene Blue Adsorption Study Using Reeds. Ind. J. Chem. Anal. Vol 1(1) : 9-19.
  8. Karan, T., Gonulalan, Z., Erenler, R., Kolemen, U., & Eminagaoglu, O. 2024. Green synthesis of silver nanoparticles using Sambucus ebulus leaves extract: Characterization, quantitative analysis of bioactive molecules, antioxidant and antibacterial activities. Journal of Molecular Structure, 1296, 136836.
  9. Kasim, S., P. Taba, Ruslan dan Romianto. 2020. Synthesis of Silver Nanoparticles Using Water Hyacinth (Eichornia crassipes) Leaf Extract as a Bioreductant. KOVALEN: Jurnal Riset Kimia, 6 (2):126–133.
  10. Komala, S. N., B.H. Budianto dan E. Basuki. 2018. Toxicity Study: Methanol Extract of Ambon Banana Weevil (Musa acuminata L. cv. Gros Michel) against Aedes aegypti (Diptera: Culcidae). ASPIRATOR - Journal of Vector- borne Disease Studies. 10 (2):93–102.
  11. Marimuthu, S., Antonisamy, A. J., Malayandi, S., Rajendran, K., Tsai, P. C., Pugazhendhi, A., & Ponnusamy, V. K. 2020. Silver nanoparticles in dye effluent treatment: A review on synthesis, treatment methods, mechanisms, photocatalytic degradation, toxic effects and mitigation of toxicity. Journal of Photochemistry and Photobiology B: Biology, 205, 111823.
  12. Masakke, Y., Sulfikar dan M. Rasyid. 2015. Biosynthesis of Silver Nanoparticles Using Methanol Extract of Mangosteen Leaves (Garcinia mangostana L.) Biosynthesis of Silver Nanoparticles using Methanol Extract of Mangosteen Leaves (Garcinia mangostana L.). Jurnal Sainsmat. 4 (1):28–41.
  13. Mechouche, M. S., Merouane, F., Messaad, C. E. H., Golzadeh, N., Vasseghian, Y., & Berkani, M. 2022. Biosynthesis, characterization, and evaluation of antibacterial and photocatalytic methylene blue dye degradation activities of silver nanoparticles from Streptomyces tuirus strain. Environmental Research, 204, 112360.
  14. Momeni, S. S., Nasrollahzadeh, M., & Rustaiyan, A. 2017. Biosynthesis and application of Ag/bone nanocomposite for the hydration of cyanamides in Myrica gale L. extract as a green solvent. Journal of colloid and interface science, 499, 93-101.
  15. Rahma, A. N., & Suratno, S. 2023. Optimization of Silver Nanoparticle Biosynthesis with Papaya (Carica Papaya L) Seed Ethanol Extract and its Evaluation on Antibacterial Effects. Walisongo Journal of Chemistry, 6(1), 12-21.
  16. Rajkumar, R., Ezhumalai, G., & Gnanadesigan, M. 2021. A green approach for the synthesis of silver nanoparticles by Chlorella vulgaris and its application in photocatalytic dye degradation activity. Environmental Technology & Innovation, 21, 101282.
  17. Saha, J., Begum, A., Mukherjee, A., & Kumar, S. 2017. A novel green synthesis of silver nanoparticles and their catalytic action in reduction of Methylene Blue dye. Sustainable Environment Research, 27(5), 245-250.
  18. Sahin Yaglioglu, A., Erenler, R., Gecer, E. N., & Genc, N. (2022). Biosynthesis of silver nanoparticles using Astragalus flavesces leaf: identification, antioxidant activity, and catalytic degradation of methylene blue. Journal of Inorganic and Organometallic Polymers and Materials, 32(10), 3700-3707.
  19. Salasa, D., H. Aritonang Dan V. S. Kamu. 2016. Synthesis of Silver (Ag) Nanoparticles with Sodium Borohydride (NABH4) Reductant Using Nata-De-Coco Matrix. Jurnal. Chem. Prog. Vol 9 (2) : 34-40.
  20. Sari. P. I., M.L. Firdaus dan R. Elvia. 2017. Fabrication Silver Nanoparticles (NPP) Using Muntingia calabura L Fruit Extract Bioreductor for Mercury Metal Analysis. ALOTROP Jurnal Pendidikan dan Ilmu Kimia. Vol 1(1) : 20-26
  21. Safaepour, M., Shahverdi, A. R., Shahverdi, H. R., Khorramizadeh, M. R., dan Gohari, A. R. 2009. Green Synthesis of Small Silver Nanoparticles Using Geraniol and Its Cytotoxicity against Fibrosarcoma-Wehi 164. Avicenna Journal of Medical Biotechnology, 1(2): 111-115.
  22. Sharifi-Rad, M., Elshafie, H. S., & Pohl, P. 2023. Green synthesis of silver nanoparticles (AgNPs) by Lallemantia royleana leaf Extract: Their Bio-Pharmaceutical and catalytic properties. Journal of Photochemistry and Photobiology A: Chemistry, 115318.
  23. Singh, S., Saikia, J. P., & Buragohain, A. K. 2013. A novel ‘green’synthesis of colloidal silver nanoparticles (SNP) using Dillenia indica fruit extract. Colloids and Surfaces B: Biointerfaces, 102, 83-85.
  24. Solomon, S. D., M. Bahadory, A.V. Jeyarajasingam, S.A. Rutkowsky dan C. Boritz. 2007. Synthesis and study of silver nanoparticles. Journal of Chemical Education. 84 (2):322–325.
  25. Taba, P., N.Y. Parmitha dan S. Kasim. 2019. ynthesis of Silver Nanoparticles Using Bay Leaf Extract (Syzygium polyanthum) as a bioreductant and testing its activity as an antioxidant. Indo. J. Chem. Res.7(1):51–60.

Open Access Copyright (c) 2023 Walisongo Journal of Chemistry
Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

WJC: Walisongo Journal of Chemistry
Published by the Department of Chemistry
Faculty of Science and Technology
Universitas Islam Negeri Walisongo Semarang
Jl Prof. Dr. Hamka Kampus III Ngaliyan Semarang 50185
Website: https://journal.walisongo.ac.id/index.php/wjc
Email: wjc@walisongo.ac.id  wjc@walisongo.ac.id

ISSN: 2549-385X (Print)
ISSN: 2621-5985 (Online)




http://ready.dprd.jatimprov.go.id/images_dapil/user/toto-slot/

https://kelurahan-maleber.ciamiskab.go.id/wp-content/sthailand/

https://ekinerja.uho.ac.id/vendors/btogel/

http://ready.dprd.jatimprov.go.id/images_dapil/blog/sthailand/

http://gordonsserver.zyns.com/

https://awas.ojk.go.id/send_attachments/

https://ekinerja.uho.ac.id/temp/cgacor/

https://ekinerja.uho.ac.id/upload/-/toto-slot/

https://pafikonawemepokoasu.org/

https://alumni.eng.uho.ac.id/storage/produk/

https://alumni.eng.uho.ac.id/storage/jobs-cover/sthailand/

https://thailand.penerimaan.uinbanten.ac.id/

https://alumni.eng.uho.ac.id/storage/sgacor/

https://alumni.eng.uho.ac.id/storage/slot88/

https://lms-bima.bkkbn.go.id/js/sthailand/

https://akg.fkm.ui.ac.id/wp-content/cache/toto-slot/

https://keplinggau.poltekkespalembang.ac.id/wp-content/uploads/2024/sthailand/

https://sinaubareng.jatengprov.go.id/-/sgacor/

https://lms-bima.bkkbn.go.id/fonts/rupiahslot/https://lms-bima.bkkbn.go.id/storage/toto-slot/

https://e-anjab.lampungutarakab.go.id/fonts/sthailand/

https://ppid.kaltimprov.go.id/uploads/produk/toto-slot/

https://ppid.kaltimprov.go.id/images/cgacor/

https://ppid.kaltimprov.go.id/sthailand/

https://repository.unib.ac.id/produk/sthailand/

https://repository.unib.ac.id/toto-slot/

https://pariwisata.kalteng.go.id/images/-/toto-slot/

https://pariwisata.kalteng.go.id/images/agenda/sthailand/

https://fassikolae.stifa.ac.id/login/toto-slot/

https://fassikolae.stifa.ac.id/tag/sthailand/

https://fassikolae.stifa.ac.id/mod/sdemo/

http://rsudwzjohanes.nttprov.go.id/web3/user/sdemo/

https://elearning.ummat.ac.id/mod/cgacor/

 https://elearning.ummat.ac.id/mod/cgacor/

https://elearning.ummat.ac.id/repository/toto-slot/

http://digilib.fe.unj.ac.id/bl/user/cgacor/

http://digilib.fe.unj.ac.id/bl/media/toto-slot/

http://digilib.fe.unj.ac.id/bl/tag/sdana/

http://digilib.fe.unj.ac.id/bl/login/sovo/

https://conference.unesa.ac.id/files/cgacor/

https://dpmptsp.inhilkab.go.id/wp-content/sgacor/

 https://repository.unida.ac.id/-/7gacor/

https://pmddukcapil.kepriprov.go.id/-/sthailand/

https://pmddukcapil.kepriprov.go.id/-/sgacor/

https://pmddukcapil.kepriprov.go.id/-/toto-slot/

https://jom.uin-suska.ac.id/-/cgacor/

https://jom.uin-suska.ac.id/-/sthailand/

https://jom.uin-suska.ac.id/-/toto-slot/

https://ukmc.feb.ui.ac.id/sgacor/

https://ukmc.feb.ui.ac.id/-/toto-slot/

https://ukmc.feb.ui.ac.id/-/sthailand/

 https://jurnal.ulb.ac.id/files_la_ulb-9809-exkripsi-file/journals/24/-/sthailand/

https://proceeding.unesa.ac.id/sthailand/

https://proceeding.unesa.ac.id/toto-slot/

https://www.revistas.uc.edu.ve/-/btogel/

https://www.revistas.uc.edu.ve/-/sthailand/

https://jurnal.ulb.ac.id/files_la_ulb-9809-exkripsi-file/journals/24/-/toto-slot/

https://phase.farmasi.ui.ac.id/-/s4d/

https://phase.farmasi.ui.ac.id/-/sgacor/

https://phase.farmasi.ui.ac.id/-/sthailand/

https://ekinerja.uho.ac.id/upload/lampiran_f/sgacor/

 

 

 

CASATOTO


apps