Effect of Molarity on Double Layer Photocatalytic Activity ZnO/ZnO:Ag for Metanil Yellow Degradation

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Published: Jul 30, 2023
DOI: https://doi.org/10.21580/perj.2023.5.1.13301
Keywords:
Double layer, Methanil Yellow, Molarity, ZnO/ZnO, Ag

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Sheilla Rully Anggita
Universitas Islam Negeri Walisongo Semarang
Hamdan Hadi Kusuma
Universitas Islam Negeri Walisongo Semarang
Heni Sumarti
Universitas Islam Negeri Walisongo Semarang
Sosiawati Teke
Jeju National University

Abstract

Double layer (DL) ZnO/ZnO:Ag has been synthesized with variations in molarity of 0.1, 0.3, 0.5,  and 0.7 M and its application as a degrading agent for methanil yellow dye. This study aims to determine the effect of the molarity of the DL ZnO/ZnO:Ag on crystallinity and photocatalytic activity for methanil yellow degradation. DL ZnO/ZnO:Ag was synthesized using sol-gel technique and deposited with spray coating technique. The results of DL ZnO/ZnO:Ag were characterized by XRD to determine the crystallinity and particle size. The photocatalytic activity was carried out by immersing the DL ZnO/ZnO:Ag layer in 10 ppm methanil yellow solution and irradiating it with UV light for 4 hours and then tested using UV-Vis spectroscopy to get the percentage of methanil yellow degradation. The results showed that the crystallinity of the DL ZnO/ZnO:Ag for all molarity variations had a hexagonal wurtzite structure. Grains size increase as molarity increases from 0.1 to 0.5 M. However, if the concentration continues to be increased to 0.7M, the grain size decreases. Photocatalytic activity is increasing every hour, as indicated by the increasing percentage of degradation. Precursor in 0.5 M has the maximum percentage of degradation is 25.32%.

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Vol. 5 No. 1 (2023)
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Author Biography

Sheilla Rully Anggita, Universitas Islam Negeri Walisongo Semarang

References

Afaah, A. N., Asib, N. A. M., Umbaidilah, S. Z., Rusop, M., & Khusaimi, Z. (2019). The effect of annealing temperature on the properties of Ag+ doped ZnO thin films. AIP Conference Proceedings, 2151(August). https://doi.org/10.1063/1.5124650

Al-Jawad, S. M. H., Sabeeh, S. H., Taha, A. A., & Jassim, H. A. (2018). Studying structural, morphological and optical properties of nanocrystalline ZnO:Ag films prepared by sol–gel method for antimicrobial activity. Journal of Sol-Gel Science and Technology, 87(2), 362–371. https://doi.org/10.1007/s10971-018-4724-9

Ali, S. M., Farooq, W. A., Baig, M. R., Shar, M. A., Atif, M., Alghamdi, S. S., AlGarawi, M. S., Naeem-Ur-Rehman, & Aziz, M. H. (2015). Structural and optical properties of pure and Ag doped ZnO thin films obtained by sol gel spin coating technique. Materials Science- Poland, 33(3), 601–605. https://doi.org/10.1515/msp-2015-0091

Ali, T., Ahmed, A., Alam, U., Uddin, I., Tripathi, P., & Muneer, M. (2018). Enhanced photocatalytic and antibacterial activities of Ag-doped TiO2 nanoparticles under visible light. Materials Chemistry and Physics, 212, 325–335. https://doi.org/10.1016/j.matchemphys.2018.03.052

Anggita, S. R., Ghozali, A., & Kusuma, H. H. (2021). Effect of concentration double layer ZnO/ZnO:Ag on optical and photocatalytic properties. IOP Conference Series: Earth and Environmental Science, 1796(1). https://doi.org/10.1088/1742-6596/1796/1/012106

Anggita, S. R., & Sutanto, H. (2016). Preparation and Microstructure of Ag Doped on ZnO. J. Nat. Science & Math Res., 2(2), 148–152.

Azizi, S., Ahmad, M. B., Hussein, M. Z., & Ibrahim, N. A. (2013). Synthesis, antibacterial and thermal studies of cellulose nanocrystal stabilized ZnO-Ag heterostructure nanoparticles. Molecules, 18(6), 6269–6280. https://doi.org/10.3390/molecules18066269

Baneto, M., Enesca, A., Lare, Y., Jondo, K., Napo, K., & Duta, A. (2014). Effect of precursor concentration on structural, morphological and opto-electric properties of ZnO thin films prepared by spray pyrolysis. Ceramics International, 40(6), 8397–8404. https://doi.org/10.1016/j.ceramint.2014.01.048

Baruah, S., Pal, S. K., & Dutta, J. (2012). Nanostructured Zinc Oxide for Water Treatment. Nanoscience and Technology-Asia, 2(2), 90–102. https://doi.org/10.2174/2210681211202020090

Georgekutty, R., Seery, M. K., & Pillai, S. C. (2008). A highly efficient Ag-ZnO photocatalyst: Synthesis, properties, and mechanism. Journal of Physical Chemistry C, 112(35), 13563–13570. https://doi.org/10.1021/jp802729a

Ghosh, D., Singha, P. S., Firdaus, S. B., & Ghosh, S. (2017). Metanil yellow: The toxic food colorant. Asian Pacific Journal of Health Sciences, 4(4), 65–66. https://doi.org/10.21276/apjhs.2017.4.4.16

Gita Bhernama, B., Safni, S., & Syukri, S. (2017). Degradasi Zat Warna Metanil Yellow dengan Penyinaran Matahari dan Penambahan Katalis TiO2-SnO2. Lantanida Journal, 3(2), 116. https://doi.org/10.22373/lj.v3i2.1653

Goel, A., & Chaudhary, M. (2018). Highly dispersed PVP-supported Ir–Ni bimetallic nanoparticles as high performance catalyst for degradation of metanil yellow. Bulletin of Materials Science, 41(3). https://doi.org/10.1007/s12034-018-1591-5

Hosseini, S. M., Sarsari, I. A., Kameli, P., & Salamati, H. (2015). Effect of Ag doping on structural, optical, and photocatalytic properties of ZnO nanoparticles. Journal of Alloys and Compounds, 640, 408–415. https://doi.org/10.1016/j.jallcom.2015.03.136

Jabeen, M., Javed, M. T., Ashraf, M. W., Tayyaba, S., Kumar, R. V, & Okara, D. (2017). Synthesis of ZnO Nanorods on Aluminum Foil for Ethanol Sensing at Low Temperature. Digest Journal of Nanomaterials and Biostructures, 12(4), 981–992.

Jia, Z. G., Peng, K. K., Li, Y. H., & Zhu, R. S. (2012). Preparation and photocatalytic performance of porous ZnO microrods loaded with Ag. Transactions of Nonferrous Metals Society of China (English Edition), 22(4), 873–878. https://doi.org/10.1016/S1003-6326(11)61259-4

Karunakaran, C., Rajeswari, V., & Gomathisankar, P. (2011). Optical, electrical, photocatalytic, and bactericidal properties of microwave synthesized nanocrystalline Ag-ZnO and ZnO. Solid State Sciences, 13(5), 923–928. https://doi.org/10.1016/j.solidstatesciences.2011.02.016

Masruroh, Manggara, A. B., Lapailaka, T., & Triandi, R. (2013). Penentuan Ukuran Kristal (Crystallite Size) Lapisan Tipis Pzt Dengan Metode Xrd Melalui Pendekatan Persamaan Debye Scherrer. Erudio Journal of Educational Innovation, 1(2), 24–29. https://doi.org/10.18551/erudio.1-2.4

Masunga, N., Mamba, B. B., & Kefeni, K. K. (2020). Trace samarium doped graphitic carbon nitride photocatalytic activity toward metanil yellow dye degradation under visible light irradiation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 602(April), 125107. https://doi.org/10.1016/j.colsurfa.2020.125107

Mohammadi, M., Rokn-Abadi, M. R., & Arabshahi, H. (2010). Investigations on impact of post-heat temperature on structural, optical and electrical properties of Al-doped ZnO. Indian Journal of Science and Technology, 3(2), 110–112.

Nagayasamy, N., Gandhimathination, S., & Veerasamy, V. (2013). The Effect of ZnO Thin Film and Its Structural and Optical Properties Prepared by Sol-Gel Spin Coating Method. Open Journal of Metal, 03(02), 8–11. https://doi.org/10.4236/ojmetal.2013.32A2002

Priyadharshini, S. S., Shubha, J. P., Shivalingappa, J., Adil, S. F., Kuniyil, M., Hatshan, M. R., Shaik, B., & Kavalli, K. (2022). Photocatalytic Degradation of Methylene Blue and Metanil Yellow Dyes Using Green Synthesized Zinc Oxide (ZnO) Nanocrystals. Crystals, 12. https://doi.org/doi.org/10.3390/ cryst12010022

Sakthivelu, A., Saravanan, V., Anusuya, M., & Prince, J. J. (2011). Structural, Morphological and Optical Studies of Molarity Based ZnO Thin Film. Journal of Ovonic Research, 7(1), 1–7.

Sangari, N. U. (2018). Role of β-cyclodextrin in enhanced photocatalytic decolorization of metanil yellow dye with TiO2. Asian Journal of Chemistry, 30(10), 2294–2298. https://doi.org/10.14233/ajchem.2018.21468

Sutanto, H., Wibowo, S., Hidayanto, E., Nurhasanah, I., & Hadiyanto, H. (2015). Synthesized of Double Layer Thin Film ZnO/ZnO:Ag by Sol-Gel Method for Direct Blue 71 Photodegradation. Reaktor, 15(3), 175–181. https://doi.org/10.14710/reaktor.15.3.175-181

Taheri, M., Abdizadeh, H., & Golobostanfard, M. R. (2017). Formation of urchin-like ZnO nanostructures by sol-gel electrophoretic deposition for photocatalytic application. Journal of Alloys and Compounds, 725, 291–301. https://doi.org/10.1016/j.jallcom.2017.07.173

Tarwal, N. L., & Patil, P. S. (2011). Enhanced photoelectrochemical performance of Ag-ZnO thin films synthesized by spray pyrolysis technique. Electrochimica Acta, 56(18), 6510–6516. https://doi.org/10.1016/j.electacta.2011.05.001