Characterization of Natural Clay from Tulungagung Regency, East Java Province, Indonesia

Mike Rahayu*    -  Universitas Islam Negeri Sayyid Ali Rahmatullah Tulungagung, East Java, Indonesia
Novia Amalia Sholeha  -  School of Vocational Studies, Bogor Agricultural University (IPB University), West Java, Indonesia
Siti Rahmah  -  Chemical Engineering Department, Graduate School of Engineering, Tohoku University, Japan

(*) Corresponding Author

Natural clay is a material that has various benefits and is abundant in the environment. This research will study about the characteristics of natural clay from Tulungagung, East Java, Indonesia. This research used two samples of Natural Clay-1 (NC-1) and Natural Clay 2 (NC-2) from Tulungagung, Sidem village, Gondang district. The natural clays were dried at room temperature for 2 days then pulverized and sieved using 100 mesh sieves. X-ray diffraction (XRD), x-ray fluorescence (XRF), infrared spectroscopy (IR), and scanning electron microscopy (SEM) have been utilized to characterize the natural clay. XRF analysis revealed that the primary components of Tulungagung's natural clay are Fe, Si, and Al. Montmorillonite, quartz, and anatase are the primary natural clay minerals, as determined by XRD and FTIR. The results of the SEM indicate a non-uniform material surface.

Keywords: Natural clay; chemical composition; mineral content; morphology

  1. Asfadiyah, N. R. (2014). Sintesis dan Karakterisasi Zeolit X dari Abu Ampas Tebu dengan Variasi Rasio Molar Si/Al Menggunakan Metode Sol-Gel. Maulana Malik Ibrahim State Islamic University.
  2. Assila, O., Tanji, K., Zouheir, M., Arrahli, A., Nahali, L., Zerrouq, F., & Kherbeche, A. (2020). Adsorption studies on the removal of textile effluent over two natural eco-friendly adsorbents. Journal of Chemistry. vol. 2020, Article ID 6457825, 13 pages, 2020. https://doi.org/10.1155/2020/6457825
  3. Baloyi, J., Ntho, T., & Moma, J. (2018). Synthesis and application of pillared clay heterogeneous catalysts for wastewater treatment: A review. In RSC Advances (Vol. 8, Issue 10, pp. 5197–5211). Royal Society of Chemistry. https://doi.org/10.1039/c7ra12924f
  4. Boulahbal, M., Malouki, M. A., Canle, M., Redouane-Salah, Z., Devanesan, S., AlSalhi, M. S., & Berkani, M. (2022). Removal of the industrial azo dye crystal violet using a natural clay: Characterization, kinetic modeling, and RSM optimization. Chemosphere, 306. https://doi.org/10.1016/j.chemosphere.2022.135516
  5. Darwanto, Suwito, & Fatimah, H. (2019). Karakterisasi Lempung Alam Asal Distrik Tanah Miring Kabupaten Merauke sebagai Adsorben Bleaching CPO (Crude Palm Oil). Avogadro Jurnal Kimia, 3(1), 35–42.
  6. Eddarai, E. M., el Mouzahim, M., Boussen, R., Bellaouchou, A., Guenbour, A., & Zarrouk, A. (2022). Chitosan-kaolinite clay composite as durable coating material for slow release NPK fertilizer. International Journal of Biological Macromolecules, 195, 424–432. https://doi.org/10.1016/j.ijbiomac.2021.12.055
  7. Gu, S., Kang, X., Wang, L., Lichtfouse, E., & Wang, C. (2019). Clay mineral adsorbents for heavy metal removal from wastewater: a review. In Environmental Chemistry Letters (Vol. 17, Issue 2, pp. 629–654). Springer. https://doi.org/10.1007/s10311-018-0813-9
  8. Huggett, J. M. (2015). Clay Minerals. In Reference Module in Earth Systems and Environmental Sciences (pp. 1–8). Elsevier. https://doi.org/10.1016/B978-0-12-409548-9.09519-1
  9. Jackson, M. L. (1957). Frequency Distribution Of Clay Minerals In Major Great Soil Groups As Related to The Factors Of Soil Formation. Clay and Clays Mineral, 6, 133–143.
  10. Karelius, & Asi, N. B. (2018a). Sintesis Dan Karakterisasi Komposit Magnetik Lempung Putih Asal Kalimantan Tengah Sebagai Adsorben Zat Warna Pada Limbah Cair. Jurnal Ilmiah Kanderang Tingang, 9(1), 51–66.
  11. Karelius, & Asi, N. B. (2018b). Sintesis Dan Karakterisasi Komposit Magnetik Lempung Putih Asal Kalimatan Tengah Sebagai Adsorben Zat Warna Pada limbah Cair. Jurnal Ilmiah Kanderang Tingang, 9(1), 51–66.
  12. Musawwa, M. M., Ardiyanto, N. R. N., Lestari, A., Yusuf, A. K., & Solehudin, M. (2022). Synthesis of Zeolite Based Material With Aluminum Sources from Used Beverage Cans for Hard Water Desalination. Walisongo Journal of Chemistry, 5(1), 37–44. https://doi.org/10.21580/wjc.v5i1.9172
  13. Sadiana, I. M., Fatah, A. H., & Karelius. (2018). Aktivasi Dan Karakterisasi Lempung Alam Asal Kalimantan tengah Sebagai Salah Satu Alternatif Bahan Adsorben. Seminar Nasional Pendidikan, 216–226.
  14. Schwertmann, U. (1988). Occurence And Formation Of Iron Oxides In Various Pedoenvironments. In Iron in Soils and Clay Minerals (pp. 267–308).
  15. Setyaningrum, D., Sujiat, S., & Azizah, A. N. (2021). Characterizayiom Of Clay Materials Used For Pottery Purposes From Rendeng, Malo, Bojonegoro. Jurnal Neutrino, 14(1), 6–11. https://doi.org/10.18860/neu.v14i1.12753
  16. Side, S., & Putri, S. E. (2022). Characterization of Natural Clay from Gowa Regency, South Sulawesi Province, Indonesia. Jurnal Akademika Kimia, 11(2), 72–76. https://doi.org/10.22487/j24775185.2022.v11.i2.pp72-76
  17. Tahya, C. Y., Cornelia, M., Siregar, T. M., & Taipabu, M. I. (2022). Adsorption of Copper Ion from Acidic Wastewater by Local Natural Zeolite. Walisongo Journal of Chemistry, 5(2), 136–144. https://doi.org/10.21580/wjc.v5i2.11714
  18. Uddin, M. K. (2017). A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. In Chemical Engineering Journal (Vol. 308, pp. 438–462). Elsevier B.V. https://doi.org/10.1016/j.cej.2016.09.029
  19. Yanti, P. H., & Muhktar, D. A. (2015). Karakterisasi Lempung Alam Desa Gema Teraktifasi Fisika. Chem. Prog, 8(1). https://doi.org/10.35799/cp.8.1.2015.9396
  20. Zhao, Y., Qi, W., Chen, G., Ji, M., & Zhang, Z. (2015). Behavior of Cr(VI) removal from wastewater by adsorption onto HCl activated Akadama clay. Journal of the Taiwan Institute of Chemical Engineers, 50, 190–197. https://doi.org/10.1016/j.jtice.2014.12.016

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WJC: Walisongo Journal of Chemistry
Published by the Department of Chemistry
Faculty of Science and Technology
Universitas Islam Negeri Walisongo Semarang
Jl Prof. Dr. Hamka Kampus III Ngaliyan Semarang 50185
Website: https://journal.walisongo.ac.id/index.php/wjc
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ISSN: 2549-385X (Print)
ISSN: 2621-5985 (Online)




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